I think this should work. Put it in the htaccess in the root folder for your sub domain or possibly in the directory for the website (sorry, a bit out of touch with code these days!)
Options +FollowSymlinks
RewriteEngine On
RewriteBase /
#redirect whatever directory to the add-on domain
RewriteCond %{HTTP_HOST} ^sub.domain.com/whatever/? [NC]
RewriteRule ^(.*)$ http://www.correct-domain.co.uk/$1 [R=301,L]
Note, you only need the top part if you don't already have it in the htaccess file.